Operational security is the discipline of not defeating your own tools. Encryption, Tor, and hardened devices fail open when the person using them reuses a username, mentions their hometown, or answers a well-crafted phone call. Historically, that is how nearly everyone gets caught. The Darwin Awards section is the case-study companion to this one.
OPSEC is also the most transferable skill on this site: the same thinking protects an activist, a business negotiation, and an ordinary person leaving an abusive relationship.